At the end of a match, Marvel Rivals gives players the opportunity to watch their match highlight. It’s your own personal best play from the previous match, whether that’s a massive multi-kill or a crucial ultimate ability use.
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While Marvel Rivals doesn’t show a “play of the game” after a match like its competitor, Overwatch, it does give each player the option to watch their own match highlight, as well as the option to watch their teammate’s. The button to watch it isn’t immediately visible on the end-of-match screen, but it’s only a few clicks away.
After a match ends, you must give yourself or a teammate a "thumbs up". Once you do, the cursor will change to a play button, allowing you to view match highlights for that player (including your own) by clicking on the player's name.
Once you click on the player’s name, their highlight will play after a brief second of loading. The end of match screen lasts quite a while after a match has finished, so you have the opportunity to watch multiple highlights of your team.